Asbestos in drinking water and in old asbestos cement water pipes
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Asbestos in drinking water and in old asbestos cement water pipes

Asbestos in drinking water usually comes from asbestos cement pipes. Why the WHO does not set a limit value and when old pipes become a problem.

In Germany, asbestos in water almost always comes from one source: old drinking water pipes made of asbestos cement. Around 6.7% of the German pipe network still consists of this material. The danger of asbestos is well documented. However, it comes from inhaling the fibres. For exposure via drinking water, the World Health Organization (WHO) and German authorities assess the data differently. This guide separates the two and shows when an asbestos cement pipe becomes a problem.

What is asbestos?

Asbestos is the collective name for six naturally occurring, fibrous silicate minerals. The Umweltbundesamt (UBA, German Environment Agency) describes asbestos as fibrous minerals from rock. The six minerals include chrysotile (white asbestos), crocidolite (blue asbestos), amosite, anthophyllite, tremolite and actinolite.

The fibres are resistant to heat and acid, do not rot and can be split into fine fibres. This is exactly what made the mineral attractive for building materials, above all for asbestos cement. According to the UBA, the asbestos content of asbestos cement is around 10 to 15%. The fibres are firmly bound in the cement. In Germany, the manufacture, sale and use of asbestos have been banned since 31 October 1993. The EU-wide ban followed in 2005.

Why asbestos is dangerous

Asbestos endangers health mainly via the respiratory tract. Inhaled asbestos fibres are permanently deposited in the lungs, irritate them for decades and cause cancer. The International Agency for Research on Cancer (IARC) classifies all six types of asbestos in Group 1, i.e. as definitely carcinogenic to humans.

Four diseases are recognised in Germany as asbestos-related occupational diseases: pulmonary asbestosis, pleural asbestosis, lung cancer and mesothelioma. Mesotheliomas are tumours of the pleura and the peritoneum. They can develop even after brief contact with asbestos and are usually fatal. Often more than 40 years pass between the uptake of the fibres and the onset of the disease. Crocidolite (blue asbestos) is considered particularly carcinogenic.

The evidence for the cancer risk all comes from inhalation. The route of danger is via the lungs, not the stomach. A different assessment applies to oral intake via drinking water. You will find it further down in this guide.

Where asbestos in drinking water comes from

The main source of asbestos in drinking water is asbestos cement pipes in the water supplier's network. This is what the WHO states in its fact sheet on asbestos in drinking water (as of 2021). The WHO also names three other routes: the weathering of asbestos-bearing minerals and ores, industrial wastewater and air pollution.

A fourth route concerns rainwater. If rainwater is collected from poorly sealed asbestos cement roofs, it can contain asbestos fibres. This applies to rainwater tanks and cisterns, not to the public drinking water supply.

To give an idea of the scale: according to the WHO, levels in drinking water are usually below 1 million fibres per litre. More than 10 million fibres per litre are rare. The WHO reports higher levels where asbestos cement pipes are in use. At the same time, it points out that data on occurrence are sparse.

Asbestos cement water pipes in Germany

Around 6.7% of drinking water pipes in Germany are made of asbestos cement. This figure comes from the pipe network statistics of the Deutscher Verein des Gas- und Wasserfaches (DVGW, German Technical and Scientific Association for Gas and Water). The pipes were laid mainly in the 1950s and 1960s. Estimates put the total at around 30,000 kilometres. There is a particular concentration in Schleswig-Holstein.

Since 1 January 1995, no new asbestos cement pipes may be laid. Old pipes may remain in service. The DVGW justifies this on the grounds that contact with drinking water poses no risk to consumers' health.

The pipes are ageing nonetheless. Manufacturers state a service life of 60 to 70 years. On this basis, all asbestos cement pipes would, in theory, have to be replaced by 2050. The DVGW research project W 201721 therefore developed a method for this: water suppliers chemically test the condition of pipe samples that have been removed and estimate the remaining service life.

What Eternit and AZ pipe mean for water pipes

Eternit is a brand name, not the name of a material. The Austrian industrialist Ludwig Hatschek filed a patent application for the process in 1900. In 1903, he had Eternit protected as a word mark. The name comes from the Latin “aeternus”, meaning eternal. The material behind it is called fibre cement.

Until the early 1990s, the fibre in this fibre cement was asbestos. The Eternit water pipes that still lie in the ground today date from this period. AZ stands for Asbestzement (asbestos cement). AZ-Rohr and AZ-Leitung (AZ pipe, AZ main) are the abbreviations that water suppliers use in their network plans.

Important for context: today's Eternit contains no asbestos. Since the ban in 1993, fibre cement products sold under this brand name have been made with plastic or cellulose fibres. An Eternit product from a DIY store is therefore no indication of asbestos. An Eternit pipe from the 1960s, on the other hand, certainly is.

Does asbestos dissolve in water?

Asbestos is not water-soluble. Asbestos is a fibrous mineral, not a salt. The fibres are chemically very resistant. They withstand acids and alkalis and practically do not decompose in the environment. So water does not dissolve the fibres in the way that it dissolves salt.

What can be attacked is something else: the cement in which the fibres are embedded. Lime-dissolving water can attack the cement matrix of an asbestos cement pipe from the inside. If it leaches out binder in the process, individual asbestos fibres come loose mechanically and get into the water. The fibres are then suspended in the water as particles; they are not dissolved.

The difference between particles and dissolved substances shapes the Trinkwasserverordnung (German Drinking Water Ordinance): it does not regulate the asbestos content, but the aggressiveness of the water towards the cement.

When an asbestos cement pipe becomes a problem

An asbestos cement pipe becomes a problem in 2 cases: when lime-dissolving water attacks the cement, or when someone damages the pipe mechanically. As long as the water is in lime-carbonic acid equilibrium, a protective layer forms on the cement surface. The fibres then remain bound.

Very soft water in particular dissolves lime. Soft water is low in lime and can leach lime out of the cement. Hard water tends to deposit lime instead. This is why water hardness in the supply area is an important factor for asbestos cement pipes.

This is exactly where the Drinking Water Ordinance (TrinkwV) comes in. Under Annex 3, the calculated calcite dissolution capacity at the waterworks outlet must not exceed 5 mg/l CaCO₃. This is considered to be met if the pH value at the waterworks outlet is at least 7.7. Downstream of points where water from several waterworks is mixed, a maximum value of 10 mg/l applies in the network. The permissible pH range for drinking water is between 6.5 and 9.5.

The WHO explicitly names one limitation: if a pipe is already damaged, late corrosion control will no longer stop fibres from being released. The WHO therefore advises water suppliers to map asbestos cement pipes, check their condition and replace severely damaged pipes with asbestos-free ones.

Limit values for asbestos in drinking water

There is no limit value for asbestos in drinking water in Germany or the EU. The WHO has not set a guideline value either. The USA, on the other hand, has regulated asbestos with a fixed maximum level since 1992. Germany instead regulates it indirectly via the calcite dissolution capacity.

RegulationValue for asbestosApproach
Drinking Water Ordinance (Germany)no limit valueCalcite dissolution capacity max. 5 mg/l CaCO₃ at the waterworks outlet
WHO Guidelines for Drinking-water Qualityno guideline value (as of 2021)no reliable evidence of a hazard from oral intake
US Environmental Protection Agency (EPA)7 million fibres per litre (fibres longer than 10 µm)binding maximum contaminant level (MCL), in force since 1992
EU Directive 2023/2668 (workplace)0.01 fibres per cm³ of airOccupational safety, not drinking water

The EPA sets its target value (MCLG) at the same level as the fixed maximum level, i.e. also 7 million fibres per litre. The EU occupational exposure limit is included in the table for contrast. In 2023, the EU lowered it from 0.1 to 0.01 fibres per cubic centimetre of air. It concerns inhaled fibres, not water that is drunk.

How the WHO and authorities assess oral intake

The WHO sees no reliable evidence that ingested asbestos harms health. This is precisely its reason for not setting a guideline value for asbestos in drinking water. In its fact sheet (as of 2021), the WHO puts forward 2 arguments.

First, studies on the link between asbestos in drinking water and cancer of the stomach and gastrointestinal tract are inconsistent. Some show a weak positive correlation, others find none at all. Second, in large animal studies, asbestos did not clearly increase the number of tumours in the gastrointestinal tract. According to the WHO, the two types of study taken together do not support the hypothesis that oral intake of asbestos increases the risk of cancer.

The WHO assessment is not an all-clear. Proof of safety is lacking, just as reliable proof of harm is. The USA assesses the same data more cautiously and has set a maximum level.

In Germany, a 1983 drinking water study by the Fraunhofer Institute was hotly debated. It reportedly found up to 1.57 million freely dissolved asbestos fibres per litre. As early as 1989, a Fraunhofer employee disputed this interpretation in the newspaper taz. According to him, no one had even checked which pipes the water had flowed through. What had been measured was the total content of mineral fibres, not asbestos specifically.

Working on asbestos cement pipes

The real asbestos risk is working on the pipe, not drinking the water. The WHO identifies the main problem with asbestos cement in drinking water as the people who work on the outside of the pipes, for example when cutting them. This creates dust, and they breathe that dust in.

The same rule applies in the home. If an asbestos cement drainpipe or water pipe is blocked or damaged or needs to be shortened, the work should be left to a specialist company. The Gefahrstoffverordnung (German Hazardous Substances Ordinance) and the Technical Rules for Hazardous Substances (TRGS) 519 apply here. The DVGW has revised its worksheet W 396 on the renewal and repair of asbestos cement pipes. In it, the DVGW recognises a low-emission tapping method.

Disposal is also regulated. Material containing asbestos is hazardous waste and may only be disposed of by licensed companies. Moistening binds the dust and is standard practice in asbestos work, but it is no substitute for protective equipment or a specialist company.

How to recognise an asbestos cement pipe

The local water supplier can provide information about asbestos cement pipes in the network. It keeps network plans showing the pipe material for each section. There, asbestos cement pipes are listed as AZ pipes or AZ mains. Asking the supplier is the quickest way to get a reliable answer.

For the pipe on your own property, the year of construction provides a first clue. If it was built before 1995, asbestos cement is possible. Only a material analysis by a specialist company provides certainty, not a layperson's inspection. Owners and companies can find recommendations from the DVGW on handling drinking water pipes made of asbestos cement.

Filters against asbestos fibres in water

Asbestos fibres can be filtered out of water mechanically. For conventional water treatment with flocculation and filtration, the WHO states a retention rate of over 99%, provided the process is optimised. The US Environmental Protection Agency (EPA) has approved 3 methods for asbestos: flocculation with filtration, direct and diatomite filtration, and corrosion control. Corrosion control does not filter. It keeps the cement intact so that the fibres are not released in the first place.

Asbestos fibres are particles, not a dissolved substance. That is why pore size is decisive. Membrane processes separate on exactly this basis: reverse osmosis has the finest pores, nanofiltration is one level above, ultrafiltration one level higher still. For household filters, NSF/ANSI 53 is a test standard with its own asbestos class. Certified systems must retain 99% of fibres longer than 10 µm. Checking for this test class tells you more than general filter advertising.

Alb Filter uses 2 technologies that act differently on particles and dissolved substances. The NANO cartridge works with ultrafiltration and a pore size of 0.1 µm. It is designed for particles and germs. The ACTIVE+ cartridge uses sintered activated carbon. The guide What is activated carbon explains how it works. The overview of filtration technologies and filter processes shows how membrane and adsorption processes differ.

Besides asbestos, other substances in tap water also play a role. The guide to heavy metals in tap water explains which pollutants these are and where they come from. For particles in the nanometre range, the article on the microplastics filter for drinking water is worth reading.

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Frequently asked questions

Is asbestos water-soluble?

Asbestos is not water-soluble. Asbestos fibres are chemically resistant to acids and alkalis and do not decompose in water. However, they can come loose from a corroded cement matrix as particles and are then suspended in the water.

Is it dangerous to drink or eat asbestos?

The WHO sees no reliable evidence that ingested asbestos harms health and has therefore not set a guideline value for drinking water. The proven cancer risks from asbestos stem from inhaling the fibres.

Is showering with water containing asbestos dangerous?

When showering or humidifying the air, asbestos fibres from tap water get into the indoor air. According to the WHO's assessment, this is unlikely to be of any significance for health. The risk from inhalation comes from dust produced when working on the material, not from water vapour.

Can asbestos be bound with water?

Moistening binds asbestos dust and prevents fibres from getting into the air. That is why wetting is common practice in asbestos work under TRGS 519. However, water does not make asbestos harmless and is no substitute for a specialist company.

Is rainwater from an asbestos roof contaminated?

According to the WHO, rainwater from inadequately sealed asbestos cement roofs can contain asbestos fibres. This is relevant for rainwater tanks and cisterns. An asbestos roof has no effect on the public drinking water supply.

Are asbestos cement waste pipes a problem?

An intact asbestos cement waste pipe does not release any fibres into the indoor air. It becomes critical in the event of damage and repairs, because cutting or drilling produces asbestos dust. Such work is carried out by a specialist company in accordance with TRGS 519.

How can you recognise an asbestos cement pipe?

Asbestos cement can only be identified with certainty through a laboratory analysis of the material. The year of construction serves as a clue: asbestos cement pipes were installed until 1995, in drinking water networks mainly in the 1950s and 1960s. The water supplier can provide information about the pipe material in the public network.

Is there asbestos in groundwater?

Asbestos can get into water through the weathering of asbestos-bearing minerals and ores. The WHO lists this natural route of entry alongside industrial wastewater and air pollution. However, asbestos cement pipes in the distribution network remain the main source of asbestos in drinking water.

Sources

  1. WHO Chemical Fact Sheet: Asbestos — explaining why the WHO does not set a guideline value for asbestos in drinking water (assessment as of 2021)
  2. WHO: Asbestos in drinking-water — as a background document to the WHO Guidelines for Drinking-water Quality
  3. Umweltbundesamt (German Environment Agency): Asbestos — on types of mineral, the asbestos content of asbestos cement and the German ban of 31 October 1993
  4. Annex 3 of the Drinking Water Ordinance — with the values for calcite dissolution capacity and pH value at the waterworks outlet
  5. DVGW research project W 201721: Condition of asbestos cement pipes — with the 6.7% share of asbestos cement in the German pipe network and the service life forecast
  6. US EPA: Consumer Fact Sheet on Asbestos — on the US maximum level of 7 million fibres per litre and the approved treatment methods
  7. Directive (EU) 2023/2668 — on lowering the occupational exposure limit for asbestos to 0.01 fibres per cubic centimetre
  8. BAuA: Asbestos information portal — on the Hazardous Substances Ordinance, TRGS 519 and the handling of asbestos-containing material
  9. Ludwig Hatschek on Wikipedia — on the invention of fibre cement and the Eternit word mark
  10. taz: Asbestos in drinking water, all clear? — with contemporary criticism of the analysis of the 1983 fibre counts

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